Product ID:FREON 113,TAPE HEAD CLEANER
MSDS Date:03/18/1986
FSC:5835
NIIN:00N009010
MSDS Number: BCRLZ

Emergency Phone: 617-646-0220

Info Phone: 617-646-0220

Cage: 15476

Telephone: 508-479-3046

Cage: 15476

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 100%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

LD50 LC50 Mixture:N/K (FP N/ORNL
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:VAPOR IS A NARCOTIC.POSS CARDIAC
SENSITIZATION TO EPINEPHRINE.SKIN:POSS DERMATITIS AS RESULT OF
REPEARED CONTACT.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHAL,INGEST:EXPOS AT 4,500 PPM FOR 30 TO 100
MIN RESULTED IN LOSS OF MANUAL DEXTERITY & VIGLANCE,CONC &
WAKEFULNESS.(EFFECTS DISAPPEARED 15 MIN AFTER END OF
EXPOS).RPTD/LRLNG EXPOS MAY CAUSE THROAT I RRIT.SKIN:LIQIUD
DISSOLVES NATURAL OILSIN SKIN.EYES:IN EYES OF RABBIT:REVERSIBLE
CONJUNCTIVITIS & MIN CORNEAL DAMAGE.
Medical Cond Aggravated by Exposure:N/K

First Aid:INHAL:REMOVE TO FRESH AIR.IF BREATHING STOPPED,GIVE ARTF
RESP.KEEP PERSON WARM & CALM.GET MD ATTN IMMED.SKIN:IMMED WASH
USING MILD SOAP & H*2O.IF LIQ MTL SOAKS THROUGH CLTHG,REMOVE IMMED
& WASH SKIN A S ABOVE.IF IRRIT PERSISTS,GET MD ATTN.EYES:FLUSH
IMMED W/ LG AMNT H*2O,LIFTING LIDS,AT LEAST 15 MIN. GET MD
ATTN.INGEST:GET MD ATTN IMMED.INDUCE VMTING IF CONSCIOUS.DO NOT
ATTEMPT TO (SEE SUP DATA)

Flash Point:NONE TO 48C,118F
Lower Limits:N/K
Upper Limits:N/K
Fire Fighting Procedures:WEAR PRESSURE DEMAND SELF-CONTAINED BREATHING
APPARATUS & FULL PROTTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE FLUORIDES,CHLORIDES & PHOSGENE .CARBON MONOXIDE ALSO
RELEASED DURING THERMAL DECOMPOSITION.

Spill Release Procedures:ABSORBENT SUCH AS VERMICULITE OR DRY
SAND.VENTILATE AREA OF SPILL/LEAK,ESPECIALLY LOW AREA WHERE HEAVY
VAPORS MAY COLLECT.
Neutralizing Agent:N/K

Handling and Storage Precautions:KEEP CONTAINER CLSD AND IN WELL
VENTILATED AREA.FREON 113 WILL ATTACK SOME TYPES OF PLASTIC,RUBBER
& COATINGS.
Other Precautions:NO SMOKING IN AREA OF USE.DO NOT USE IN GENERAL
VICINITY OF ARC WELDING,OPEN FLAMES OR HOT SURFACES.HEAT AND/OR UV
RADIATION MAY CAUSE FORMATION OF
CHLORIDES,FLUORIDE,PHOSGENE.CAUTION-MAY DISPLACE O*2 IN ENCLSD
CONFINED SPACES.(SEE SUP DAT)

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .USE NIOSH/MSHA APPROVED SUPPLIED AIR MASK OR
SCBA FOR HIGH EXPOSURES (MFR).
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:BUTYL OR NITRILE RUBBER GLOVES
Eye Protection:CHEM WORK GOGG,FACESHLD OPTIONAL
Other Protective Equipment:IF SPLASHING POSS,USE EXTRA PROTECTIVE
EQUIPMENT SUCH AS AN APRON.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN WHEN HANDLING
THIS MATERIAL.
Supplemental Safety and Health
EMER FIRST AID PROC:INDUCE AN UNCONSCIOUS PERSON TO VOMIT.FOR ALL THE
ABOVE,INFORM MD OF OTHER INFO IN THIS DATA SHEET.OTHER
PREC:GAS/VAPORS MAY ACCUMULATE IN LOW AREAS .

Boiling Pt:B.P. Text:47.6C,118F
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:284 MMHG
Vapor Density:6.5 (AIR=1
Spec Gravity:1.55 (WATER=1)
Evaporation Rate & Reference:>1 (BUTYL ACETATE=1)
Solubility in Water:0.017 G1100 G @ 20C
Appearance and Odor:CLEAR COLORLESS LIQUID
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ACTIVE METALS,POWDERED AL,ZNBE,CA.
Stability Condition to Avoid:DECOMPSITION BY FLAME,RED HOT SURFACES.
Hazardous Decomposition Products:CHLORIDES,FLUORIDES AND PHOSGENE
.CARBON MONOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .DO NOT DUMP ON GROUND.LARGE
QUANTITIES MAY BE RECLAIMED.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.